2,3-二甲氧基-5-溴吡啶
化合物英文学名
|
5-Bromo-2,3-dimethoxypyridine
|
化合物中文学名
|
2,3-二甲氧基-5-溴吡啶
|
CAS号
|
52605-98-8
|
分子式
|
C7H8BrNO2
|
分子量
|
218
|
精确质量
|
|
5-Bromo-2,3-dimethoxypyridine
|
English name of compound
|
5-Bromo-2,3-dimethoxypyridine
|
Chinese name of compound
|
2,3-二甲氧基-5-溴吡啶
|
CAS号
|
52605-98-8
|
molecular formula
|
C7H8BrNO2
|
formula weight
|
|
|
|
SAFETY DATA SHEETS
According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition
Version: 1.0
Creation Date: Aug 18, 2017
Revision Date: Aug 18, 2017
1.
Identification
1.1
GHS Product identifier
Product name
5-Bromo-2,3-dimethoxypyridine
1.2
Other means of identification
Product number
-
Other names
5-bromo-2,3-dimethoxy-pyridine
1.3
Recommended use of the chemical and restrictions on use
Identified uses
For industry use only.
Uses advised against
no data available
1.4
Supplier's details
Company
chemicalbook
Address
珠江摩尔大厦3号楼
Telephone
400-158-6606
Fax
86-10-69703845
1.5
Emergency phone number
Emergency phone number
Service hours
Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).
2.
Hazard identification
2.1
Classification of the substance or mixture
no data available
2.2
GHS label elements, including precautionary statements
Pictogram(s)
no data available
Signal word
no data available
Hazard statement(s)
no data available
Precautionary statement(s)
Prevention
no data available
Response
no data available
Storage
no data available
Disposal
no data available
2.3
Other hazards which do not result in classification
no data available
3.
Composition/information on ingredients
3.1
Substances
Chemical name
Common names and synonyms
CAS number
EC number
Concentration
5-Bromo-2,3-dimethoxypyridine
5-Bromo-2,3-dimethoxypyridine
52605-98-8
none
100%
4.
First-aid measures
4.1
Description of necessary first-aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2
Most important symptoms/effects, acute and delayed
no data available
4.3
Indication of immediate medical attention and special treatment needed, if necessary
no data available
5.
Fire-fighting measures
5.1
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2
Specific hazards arising from the chemical
no data available
5.3
Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
6.
Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
6.3
Methods and materials for containment and cleaning up
Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.
7.
Handling and storage
7.1
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.
7.2
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
8.
Exposure controls/personal protection
8.1
Control parameters
Occupational Exposure limit values
no data available
Biological limit values
no data available
8.2
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
8.3
Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Respiratory protection
Wear dust mask when handling large quantities.
Thermal hazards
no data available
9.
Physical and chemical properties
Physical state
no data available
Colour
no data available
Odour
no data available
Melting point/ freezing point
no data available
Boiling point or initial boiling point and boiling range
222.676ºC at 760 mmHg
Flammability
no data available
Lower and upper explosion limit / flammability limit
no data available
Flash point
88.471ºC
Auto-ignition temperature
no data available
Decomposition temperature
no data available
pH
no data available
Kinematic viscosity
no data available
Solubility
no data available
Partition coefficient n-octanol/water (log value)
no data available
Vapour pressure
no data available
Density and/or relative density
1.485g/cm3
Relative vapour density
no data available
Particle characteristics
no data available
10.
Stability and reactivity
10.1
Reactivity
no data available
10.2
Chemical stability
Stable under recommended storage conditions.
10.3
Possibility of hazardous reactions
no data available
10.4
Conditions to avoid
no data available
10.5
Incompatible materials
no data available
10.6
Hazardous decomposition products
no data available
11.
Toxicological information
Acute toxicity
Oral: no data available
Inhalation: no data available
Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
no data available
Aspiration hazard
no data available
12.
Ecological information
12.1
Toxicity
Toxicity to fish: no data available
Toxicity to daphnia and other aquatic invertebrates: no data available
Toxicity to algae: no data available
Toxicity to microorganisms: no data available
12.2
Persistence and degradability
no data available
12.3
Bioaccumulative potential
no data available
12.4
Mobility in soil
no data available
12.5
Other adverse effects
no data available
13.
Disposal considerations
13.1
Disposal methods
Product
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
14.
Transport information
14.1
UN Number
ADR/RID: Not dangerous goods.
IMDG: Not dangerous goods.
IATA: Not dangerous goods.
14.2
UN Proper Shipping Name
ADR/RID: unknown
IMDG: unknown
IATA: unknown
14.3
Transport hazard class(es)
ADR/RID: Not dangerous goods.
IMDG: Not dangerous goods.
IATA: Not dangerous goods.
14.4
Packing group, if applicable
ADR/RID: Not dangerous goods.
IMDG: Not dangerous goods.
IATA: Not dangerous goods.
14.5
Environmental hazards
ADR/RID: no
IMDG: no
IATA: no
14.6
Special precautions for user
no data available
14.7
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
no data available
15.
Regulatory information
15.1
Safety, health and environmental regulations specific for the product in question
Chemical name
Common names and synonyms
CAS number
EC number
5-Bromo-2,3-dimethoxypyridine
5-Bromo-2,3-dimethoxypyridine
52605-98-8
none
European Inventory of Existing Commercial Chemical Substances (EINECS)
Not Listed.
EC Inventory
Not Listed.
United States Toxic Substances Control Act (TSCA) Inventory
Not Listed.
China Catalog of Hazardous chemicals 2015
Not Listed.
New Zealand Inventory of Chemicals (NZIoC)
Not Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS)
Not Listed.
Vietnam National Chemical Inventory
Not Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)
Not Listed.
16.
Other information
Information on revision
Creation Date
Aug 18, 2017
Revision Date
Aug 18, 2017
Abbreviations and acronyms
CAS: Chemical Abstracts Service
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
IMDG: International Maritime Dangerous Goods
IATA: International Air Transportation Association
TWA: Time Weighted Average
STEL: Short term exposure limit
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
EC50: Effective Concentration 50%
References
IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
ECHA - European Chemicals Agency, website: https://echa.europa.eu/
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
化学品安全技术说明书
产品名称: 5-溴-2,3-二甲氧基吡啶
按照GB/T 16483、GB/T 17519 编制
修订日期: 2017年08月18日
最初编制日期: 2017年08月18日
版本: 1.0
第1部分 化学品及企业标识
化学品中文名:
5-溴-2,3-二甲氧基吡啶
化学品英文名:
5-Bromo-2,3-dimethoxypyridine
企业名称:
chemicalbook
企业地址:
珠江摩尔大厦3号楼
邮 编:
102206
传真:
86-10-69703845
联系电话:
400-158-6606
电子邮件地址:
info@chemicalbook.com
企业应急电话:
(24h)
产品推荐及限制用途:
For industry use only.。
第2部分 危险性概述
紧急情况概述:
无资料
GHS危险性类别:
无资料
标签要素:
象形图:
无资料
警示词:
无资料
危险性说明:
无资料
防范说明:
预防措施:
无资料
事故响应:
无资料
安全储存:
无资料
废弃处置:
无资料
物理和化学危险:
无资料
健康危害:
无资料
环境危害:
无资料
第3部分 成分/组成信息
组分
浓度或浓度范围(质量分数,%)
CAS No.
5-Bromo-2,3-dimethoxypyridine
100%
52605-98-8
第4部分 急救措施
急 救:
吸 入: 如果吸入,请将患者移到新鲜空气处。
皮肤接触: 脱去污染的衣着,用肥皂水和清水彻底冲洗皮肤。如有不适感,就医。
眼晴接触: 分开眼睑,用流动清水或生理盐水冲洗。立即就医。
食 入: 漱口,禁止催吐。立即就医。
对保护施救者的忠告:
将患者转移到安全的场所。咨询医生。出示此化学品安全技术说明书给到现场的医生看。
对医生的特别提示:
无资料。
第5部分 消防措施
灭火剂:
用水雾、干粉、泡沫或二氧化碳灭火剂灭火。
避免使用直流水灭火,直流水可能导致可燃性液体的飞溅,使火势扩散。
特别危险性:
无资料。
灭火注意事项及防护措施:
消防人员须佩戴携气式呼吸器,穿全身消防服,在上风向灭火。
尽可能将容器从火场移至空旷处。
处在火场中的容器若已变色或从安全泄压装置中发出声音,必须马上撤离。
隔离事故现场,禁止无关人员进入。收容和处理消防水,防止污染环境。
第6部分 泄露应急处理
作业人员防护措施、防护装备和应急处置程序:
建议应急处理人员戴携气式呼吸器,穿防静电服,戴橡胶耐油手套。
禁止接触或跨越泄漏物。
作业时使用的所有设备应接地。
尽可能切断泄漏源。